This lecture note will introduce the major concepts of physical chemistry
based on thermodynamics, chemical equilibrium, and kinetics. The topics include
the first law of thermodynamics, heat capacities, enthalpy, thermochemistry,
free energy, Helmholtz and Gibbs free energy; and an application of free energy
to phase transitions, mixtures, and equilibrium. Common equations and symbols
are summarized in detail, such that assimilation of knowledge is enhanced. For
students, this is a great source material for those taking courses in physical
chemistry-this book sets out clearly the structure of fundamental ideas and
solving techniques.
Such a
textbook projects an in-depth exploration of basic principles of physical
chemistry, with special emphasis on thermodynamics. Its content details basics
and advanced materials in topics that range from basic thermodynamics to the
thermodynamics of systems and mixtures, and even discusses advanced chemical
thermodynamics in detailed detail for the knowledge development of a student who
would want to understand a more complex system. It is ensured throughout the
book that to obtain clarity and explain it, there must be a systematic approach
in how thermodynamic principles apply to chemical reactions and equilibria. This
book is suitable for the students who have thirst to gain deeper insights into
the aspects of thermodynamics applied in physical chemistry.
This textbook
takes a practical approach to physical chemistry by providing an application of
the fundamental principles in real settings. The first topics in this textbook
include the first and second laws of thermodynamics, Gibbs free energy, phase
equilibria, chemical equilibrium, electrochemical principles, quantum chemistry,
and statistical mechanics. It dwells on three-dimensional systems and the
time-dependent Schrödinger equation in which quite complex chemical dynamics can
be explained in further detail. It is especially for advanced learners and helps
them achieve theoretical knowledge as well as practical insights into the
behavior of chemical systems and their interactions in various environments.