This lecture note will introduce the major concepts of physical chemistry
based on thermodynamics, chemical equilibrium, and kinetics. The topics include
the first law of thermodynamics, heat capacities, enthalpy, thermochemistry,
free energy, Helmholtz and Gibbs free energy; and an application of free energy
to phase transitions, mixtures, and equilibrium. Common equations and symbols
are summarized in detail, such that assimilation of knowledge is enhanced. For
students, this is a great source material for those taking courses in physical
chemistry-this book sets out clearly the structure of fundamental ideas and
solving techniques.
This
text follows the mainstream core principles of physical chemistry in a way that
highlights statistical thermodynamics with its applications. Starting with the
thermodynamics of ideal gases, it leads to the kinetic theory of gases and
detailed molecular behavior descriptions. The text also enters the domain of
chemical kinetics, describing reaction rates as they relate to many variables.
The book explores surface adsorption and transport phenomena, aiding in the
illustration of the comprehension of molecules in the behavior at the interface
and in motion. The book on physical chemistry was created for higher class
students. The book is a very rigorous approach to physical chemistry with clear
explanations and practical insights into molecular dynamics and thermodynamic
principles.
Author(s): Alberto Otero de la Roza, University of Oviedo
This
textbook is all-inclusive to both general and physical chemistry. It begins with
the particulate nature of matter and progresses through critical issues such as
atomic structure, chemical bonding, and behavior of gases. The text
substantially covers chemical thermodynamics and its applications in
equilibrium, acid-base chemistry, and redox reactions, which provides the
theoretical tools for understanding chemical systems. The book also covers phase
equilibria, transport properties of electrolytic solutions, the principles of
thermochemistry and chromatography; hence, it is a must-read for any student at
an advanced level pursuing chemistry.